Zoning and exsolution in alkali feldspars from Laacher See volcano (Western Germany): constraints on temperature history prior to eruption     

Smruti?Sourav?RoutEmail authorView author&#;s OrcID profile  Gerhard?W?rner 《Contributions to Mineralogy and Petrology》2018,173(11):95

Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km³ (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712^_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir.  相似文献   

The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations     

Artur?BenisekEmail authorView author&#;s OrcID profile  Edgar?Dachs 《Contributions to Mineralogy and Petrology》2018,173(11):90

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.  相似文献   

Carbon costs and benefits of France’s biomass energy production targets     

Aude?ValadeEmail authorView author&#;s OrcID profile  Sebastiaan?Luyssaert  Patrick?Vallet  Sylvestre?Njakou Djomo  Ingride?Jesus Van Der Kellen  Valentin?Bellassen 《Carbon balance and management》2018,13(1):26

  相似文献   

A comparison of windows and maximum entropy methods for MT transfer function estimation     

Carlos Emilio Moyano

Ana Marí  a Osella 《Physics of the Earth and Planetary Interiors》1990,60(1-4):62-67

The ability of the Maximum Entropy Spectral Estimate (MEM) to handle magnetotelluric signals was investigated. To this end simulations of naturally occurring signals and real data were spectral analyzed both by a standard FFT technique and by MEM. The method developed for the simulation of the time series, provides accurate amplitudes and phase, and turns out to be a good test procedure for spectral analysis methods, as they apply to MT signal processing. The final estimation of the apparent resistivity was better achieved by the FFT technique. Oscillations were observed in the estimation of the apparent resistivities by MEM.  相似文献   

IAP GCM模式大气背景环流在厄尔尼诺年的异常     

王盘兴  刘家铭 《南京气象学院学报》1991,14(4):503-509

本文分析了中国科学院大气物理研究所大气环流模式(IAP GCM)模式大气5～9月平均环流(本文称为背景环流)。结果表明;厄尔尼诺年一系列重要系统(南方涛动、瓦克环流、哈德莱环流、西太平洋副热带高压和热带辐合带)及大范围降水均发生明显异常;北半球西太平洋热带、副热带是环流异常的主要区域。它们与观测资料的分析结果基本一致,从而论证了该模式在低纬环流研究中的应用前景。  相似文献   

Analysis of the IMS Location Accuracy in Northern Eurasia and North America Using Regional and Global Pn Travel-time Tables     

Russian Federation/ United States Calibration Working Group 《Pure and Applied Geophysics》2001,158(1-2):59-77

—?Joint Research Program of Seismic Calibration of the International Monitoring System (IMS) in Northern Eurasia and North America has been signed by the Nuclear Treaty Programs Office (NTPO), Department of Defense USA, and the Special Monitoring Service (SMS) of the Ministry of Defense, Russian Federation (RF). Under the Program historical data from nuclear and large chemical explosions of known location and shot time, together with appropriate geological and geophysical data, has been used to derive regional Pn/P travel-time tables for seismic event location within the lower 48 States of the USA and the European part of the RF. These travel-time tables are up to 5?seconds faster in shields than the IASPEI91 tables, and up to 5?seconds slower in the Western USA. Relocation experiments using the regional Pn travel-time curves and surrogate networks for the IMS network generally improved locations for regional seismic events. The distance between true and estimated location (mislocation) was decreased from an average of 18.8?km for the IASPEI91 tables to 10.1?km for the regional Pn travel-time tables. However, the regional travel-time table approach has limitations caused by travel-time variations inside major tectonic provinces and paths crossing several tectonic provinces with substantially different crustal and upper mantle velocity structure.¶The RF members of the Calibration Working Group (WG): Colonel Vyacheslav Gordon (chairman); Dr. Prof. Marat Mamsurov, and Dr. Nikolai Vasiliev. The US members of the WG: Dr. Anton Dainty (chairman), Dr. Douglas Baumgardt, Mr. John Murphy, Dr. Robert North, and Dr. Vladislav Ryaboy.  相似文献   

IAP GCM模式大气波谱结构及其在厄尔尼诺年的异常     

王盘兴  刘家铭  沈素红 《南京气象学院学报》1992,(1)

本文分析了中国科学院大气物理研究所大气环流模式(IAP GCM)模式大气波谱结构(沿纬圈的谐波波谱和时域上的频率谱)及其在厄尔尼诺年的异常。结果表明,超长波是低纬波动的主要空间形式,准40天振荡在一定地理区域内显著存在,并与观测结果有一定联系,它们在厄尔尼诺年均发生明显异常。本工作对鉴定GCM性能及开发GCM的研究领域可能是一种有益的尝试。  相似文献   

Multi-spacecraft observations of heliographic structure of the solar wind speed     

W. Miyake

K. Kobayashi

K. -I. Oyama  T. Mukai

T. Abe

T. Terasawa

K. Yumoto  T. Saito

K. Hirao

A. J. Lazarus

A. D. Johnstone 《Planetary and Space Science》1988,36(12):1329-1342

Multi-spacecraft observations in the interplanetary space are used to build up a picture of the distribution of solar wind velocities in heliographic latitude and longitude. Analyses are made for the solar wind data obtained by Sakigake, Suisei, IMP-8 and Giotto between late 1985 and early 1987. Until Janaury 1986, high-speed streams were extended across the equator from the high latitudes of the heliosphere. After March 1986, high-speed streams were rarely seen on the equator. Although there remained a slight wavy pattern in latitude-longitude structure, low-speed streams were basically ranged along the equator. After January 1987, the amplitude of this wavy pattern was further diminished and low-speed regions were completely aligned to the equator.  相似文献   

研究Lienard方程闭轨线的一种方法     

胡军胜 《广东海洋大学学报》2000,20(2):56-58

结合实例分析说明 Filippov变换在研究 Lienard方程不存在闭轨线时的运用方法  相似文献   

锂矿盐湖锂分离提取新方法研究取得阶段性成果   总被引：1，自引：0，他引：1       下载免费PDF全文

宋粤华 《盐湖研究》2000,8(2):77-78

锂矿盐湖锂分离提取新方法研究”是中国科学院“西部之光”计划资助的项目,由中国科学院青海盐湖研究所青年科研小组承担并完成。该项目主要针对青海丰富的盐湖资源,以最典型和最具代表性的锂矿盐湖———东台吉乃尔盐湖为研究对象,开展盐湖卤水提锂新方法的研究。锂及其盐类是国民经济和国防建设中具有重要意义的战略物资,也是与人们生活息息相关的能源材料。近10年来,锂的国际消费量以每年6%—7%的速度增长。国内锂盐的消费市场主要在高能电池业、炼铝工业、制冷剂、制药、化学试剂和润滑剂等,近年来需求量一直呈上升趋势。锂的矿产有两大…  相似文献